{"id":2642,"date":"2024-05-24T15:38:23","date_gmt":"2024-05-24T07:38:23","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/2642"},"modified":"2024-05-24T15:38:23","modified_gmt":"2024-05-24T07:38:23","slug":"24-%e4%ba%8c%e6%b0%af%e7%94%b2%e8%8b%af","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/2642","title":{"rendered":"2,4-\u4e8c\u6c2f"},"content":{"rendered":"<p>    \t\t\t\t\t\t<img decoding=\"async\" loading=\"lazy\" class=\"alignnone size-full wp-image-2639\" src=\"https:\/\/www.shorro.cn\/wp-content\/uploads\/2024\/05\/197ca08cc11442978c231d7ca783526c.gif\" width=\"283\" height=\"227\" alt=\"2,4-\u4e8c\u6c2f\u7ed3\u6784\u5f0f\" \/><\/p>\n<p>\u7ed3\u6784\u5f0f<\/p>\n<table class=\"summary-table table table-striped table-bordered\">\n<col width=\"90\" \/>\n<tbody>\n<tr>\n<th scope=\"row\">\u7269\u7ade\u7f16\u53f7<\/th>\n<td>029P<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u5206\u5b50\u5f0f<\/th>\n<td>C7H6Cl2<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u5206\u5b50\u91cf<\/th>\n<td>161<\/td>\n<\/tr>\n<tr>\n<th scope=\"row\">\u6807\u7b7e<\/th>\n<td>\n<p>                        2,4-\u4e8c\u6c2f-1-\u7532\u57fa,<\/p>\n<p>                        2,4-\u4e8c\u6c2f(\u4e8c\u6c2f),<\/p>\n<p>                        2,4-\u4e8c\u6c2f-1-,<\/p>\n<p>                        2,4-Dichloro-1-methylbenzene,<\/p>\n<p>                        2,4-Dichloromethylbenzene,<\/p>\n<p>                        \u82b3\u9999\u65cf\u5364\u7d20\u884d\u751f\u7269<\/p>\n<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<ul class=\"nav nav-tabs\">\n<li class=\"active\"><a href=\"#bh\">\u7f16\u53f7\u7cfb\u7edf<\/a><\/li>\n<li><a href=\"#wx\">\u7269\u6027\u6570\u636e<\/a><\/li>\n<li><a href=\"#dl\">\u6bd2\u7406\u5b66\u6570\u636e<\/a><\/li>\n<li><a href=\"#st\">\u751f\u6001\u5b66\u6570\u636e<\/a><\/li>\n<li><a href=\"#fz\">\u5206\u5b50\u7ed3\u6784\u6570\u636e<\/a><\/li>\n<li><a href=\"#js\">\u8ba1\u7b97\u5316\u5b66\u6570\u636e<\/a><\/li>\n<li class=\"dropdown pull-right\">\n                    <a href=\"\" class=\"dropdown-toggle\" data-toggle=\"dropdown\">\u66f4\u591a <span class=\"caret\"><\/span><\/a><\/p>\n<ul class=\"dropdown-menu\" role=\"menu\">\n<li><a href=\"#xz\">\u6027\u8d28\u4e0e\u7a33\u5b9a\u6027<\/a><\/li>\n<li><a href=\"#zc\">\u8d2e\u5b58\u65b9\u6cd5<\/a><\/li>\n<li><a href=\"#hc\">\u5408\u6210\u65b9\u6cd5<\/a><\/li>\n<li><a href=\"#yt\">\u7528\u9014<\/a><\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<h2 id=\"bh\">\u7f16\u53f7\u7cfb\u7edf<\/h2>\n<p><b>CAS\u53f7\uff1a<\/b>95-73-8<\/p>\n<p><b>MDL\u53f7\uff1a<\/b>MFCD00000583<\/p>\n<p><b>EINECS\u53f7\uff1a<\/b>202-445-8<\/p>\n<p><b>RTECS\u53f7\uff1a<\/b>XT0730000<\/p>\n<p><b>BRN\u53f7\uff1a<\/b>1931691<\/p>\n<p><b>PubChem\u53f7\uff1a<\/b>24848696<\/p>\n<h2 id=\"wx\">\u7269\u6027\u6570\u636e<\/h2>\n<p><p>1.\u6027\u72b6\uff1a\u65e0\u8272\u900f\u660e\u6db2\u4f53\uff0c\u6709\u523a\u6fc0\u6027\u6c14\u5473\u3002<sup>[1]<\/sup><\/p>\n<p>2.\u7194\u70b9\uff08\u2103\uff09\uff1a-13.5<sup>[2]<\/sup><\/p>\n<p>3.\u6cb8\u70b9\uff08\u2103\uff09\uff1a200<sup>[3]<\/sup><\/p>\n<p>4.\u76f8\u5bf9\u5bc6\u5ea6\uff08\u6c34=1\uff09\uff1a1.25<sup>[4]<\/sup><\/p>\n<p>5.\u4e34\u754c\u538b\u529b\uff08MPa\uff09\uff1a3.59<sup>[5]<\/sup><\/p>\n<p>6.\u8f9b\u9187\/\u6c34\u5206\u914d\u7cfb\u6570\uff1a4.24<sup>[6]<\/sup><\/p>\n<p>7.\u95ea\u70b9\uff08\u2103\uff09\uff1a79.44<sup>[7]<\/sup><\/p>\n<p>8.\u5f15\u71c3\u6e29\u5ea6\uff08\u2103\uff09\uff1a\uff1e500<sup>[8]<\/sup><\/p>\n<p>9.\u7206\u70b8\u4e0a\u9650\uff08%\uff09\uff1a4.5<sup>[9]<\/sup><\/p>\n<p>10.\u7206\u70b8\u4e0b\u9650\uff08%\uff09\uff1a1.9<sup>[10]<\/sup><\/p>\n<p>11.\u6eb6\u89e3\u6027\uff1a\u4e0d\u6eb6\u4e8e\u6c34\uff0c\u53ef\u6df7\u6eb6\u4e8e\u3001\u3001\u3002<sup>[11]<\/sup><\/p>\n<\/p>\n<h2 id=\"dl\">\u6bd2\u7406\u5b66\u6570\u636e<\/h2>\n<p><p>1\u3001\u6025\u6027\u6bd2\u6027\uff1a\u5927\u9f20\u7ecf\u53e3LD50\uff1a3249mg\/kg\uff1b\u5c0f\u9f20\u7ecf\u53e3LD50\uff1a2400mg\/kg\uff1b\u8c5a\u9f20\u7ecf\u53e3LD50\uff1a5mg\/kg\uff1b<\/p>\n<p>2\u3001\u5176\u4ed6\u591a\u5242\u91cf\u6bd2\u6027\uff1a\u5927\u9f20\u7ecf\u53e3TDLo\uff1a6440mg\/kg\/2W-I\uff1b\u5927\u9f20\u7ecf\u53e3TDLo\uff1a28980mg\/ kg\/9W-I\uff1b<\/p>\n<p><strong>3.\u6025\u6027\u6bd2\u6027<strong><sup>[12]<\/sup><\/strong><\/strong>&nbsp; LD50\uff1a2400mg\/kg\uff08\u5927\u9f20\u7ecf\u53e3\uff09\uff1b2900mg\/kg\uff08\u5c0f\u9f20\u7ecf\u53e3\uff09<\/p>\n<p><strong>4.\u523a\u6fc0\u6027<\/strong>&nbsp; \u6682\u65e0\u8d44\u6599<\/p>\n<\/p>\n<h2 id=\"st\">\u751f\u6001\u5b66\u6570\u636e<\/h2>\n<p><p><strong>1.\u751f\u6001\u6bd2\u6027<strong><sup>[13]<\/sup><\/strong><\/strong>&nbsp; LC50\uff1a4.6mg\/L\uff087d\uff09\uff08\u9c7c\uff09<\/p>\n<p><strong>2.\u751f\u7269\u964d\u89e3\u6027<\/strong>&nbsp; \u6682\u65e0\u8d44\u6599<\/p>\n<p><strong>3.\u975e\u751f\u7269\u964d\u89e3\u6027<strong><sup>[14]<\/sup><\/strong><\/strong>&nbsp; \u7a7a\u6c14\u4e2d\uff0c\u5f53\u7f9f\u57fa\u81ea\u7531\u57fa\u6d53\u5ea6\u4e3a5.00\u00d710<sup>5<\/sup>\u4e2a\/cm<sup>3<\/sup>\u65f6\uff0c\u964d\u89e3\u534a\u8870\u671f\u4e3a12d\uff08\u7406\u8bba\uff09\u3002<\/p>\n<p><strong>4.\u751f\u7269\u5bcc\u96c6\u6027<strong><sup>[15]<\/sup><\/strong><\/strong>&nbsp; BCF\uff1a1000\uff08\u7406\u8bba\uff09<\/p>\n<\/p>\n<h2 id=\"fz\">\u5206\u5b50\u7ed3\u6784\u6570\u636e<\/h2>\n<p><p>1\u3001\u6469\u5c14\u6298\u5c04\u7387\uff1a40.86<\/p>\n<p>2\u3001\u6469\u5c14\u4f53\u79ef\uff08cm<sup>3<\/sup>\/mol\uff09\uff1a129.6<\/p>\n<p>3\u3001\u7b49\u5f20\u6bd4\u5bb9\uff0890.2K\uff09\uff1a316.6<\/p>\n<p>4\u3001\u8868\u9762\u5f20\u529b\uff08dyne\/cm\uff09\uff1a35.6<\/p>\n<p>5\u3001\u6781\u5316\u7387\uff1a16.20<\/p>\n<p>&nbsp;<\/p>\n<\/p>\n<h2 id=\"js\">\u8ba1\u7b97\u5316\u5b66\u6570\u636e<\/h2>\n<p><p>1.\u758f\u6c34\u53c2\u6570\u8ba1\u7b97\u53c2\u8003\u503c\uff08XlogP\uff09:\u65e0<\/P><\/p>\n<p>2.\u6c22\u952e\u4f9b\u4f53\u6570\u91cf:0<\/p>\n<p>3.\u6c22\u952e\u53d7\u4f53\u6570\u91cf:0<\/p>\n<p>4.\u53ef\u65cb\u8f6c\u5316\u5b66\u952e\u6570\u91cf:0<\/p>\n<p>5.\u4e92\u53d8\u5f02\u6784\u4f53\u6570\u91cf:\u65e0<\/p>\n<p>6.\u62d3\u6251\u5206\u5b50\u6781\u6027\u8868\u9762\u79ef0<\/p>\n<p>7.\u91cd\u539f\u5b50\u6570\u91cf:9<\/p>\n<p>8.\u8868\u9762\u7535\u8377:0<\/p>\n<p>9.\u590d\u6742\u5ea6:92.9<\/p>\n<p>10.\u540c\u4f4d\u7d20\u539f\u5b50\u6570\u91cf:0<\/p>\n<p>11.\u786e\u5b9a\u539f\u5b50\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0<\/p>\n<p>12.\u4e0d\u786e\u5b9a\u539f\u5b50\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0<\/p>\n<p>13.\u786e\u5b9a\u5316\u5b66\u952e\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0<\/p>\n<p>14.\u4e0d\u786e\u5b9a\u5316\u5b66\u952e\u7acb\u6784\u4e2d\u5fc3\u6570\u91cf:0<\/p>\n<p>15.\u5171\u4ef7\u952e\u5355\u5143\u6570\u91cf:1<\/p>\n<\/p>\n<h2 id=\"xz\">\u6027\u8d28\u4e0e\u7a33\u5b9a\u6027<\/h2>\n<p><p><strong>1.\u7a33\u5b9a\u6027<sup>[16]<\/sup><\/strong>&nbsp; \u7a33\u5b9a<\/p>\n<p><strong>2.\u7981\u914d\u7269<sup>[17]<\/sup><\/strong>&nbsp; \u5f3a\u6c27\u5316\u5242<\/p>\n<p><strong>3.\u907f\u514d\u63a5\u89e6\u7684\u6761\u4ef6<sup>[18]<\/sup><\/strong>&nbsp; \u53d7\u70ed<\/p>\n<p><strong>4.\u805a\u5408\u5371\u5bb3<sup>[19]<\/sup><\/strong>&nbsp; \u4e0d\u805a\u5408<\/p>\n<p><strong>5.\u5206\u89e3\u4ea7\u7269<sup>[20]<\/sup><\/strong>&nbsp; \u6c2f\u5316\u6c22<\/p>\n<\/p>\n<h2 id=\"zc\">\u8d2e\u5b58\u65b9\u6cd5<\/h2>\n<p><p><strong>1.\u50a8\u5b58\u6ce8\u610f\u4e8b\u9879<sup>[21]<\/sup><\/strong> \u50a8\u5b58\u4e8e\u9634\u51c9\u3001\u901a\u98ce\u7684\u5e93\u623f\u3002\u8fdc\u79bb\u706b\u79cd\u3001\u70ed\u6e90\u3002\u4fdd\u6301\u5bb9\u5668\u5bc6\u5c01\u3002\u5e94\u4e0e\u6c27\u5316\u5242\u3001\u98df\u7528\u5316\u5b66\u54c1\u5206\u5f00\u5b58\u653e\uff0c\u5207\u5fcc\u6df7\u50a8\u3002\u914d\u5907\u76f8\u5e94\u54c1\u79cd\u548c\u6570\u91cf\u7684\u6d88\u9632\u5668\u6750\u3002\u50a8\u533a\u5e94\u5907\u6709\u6cc4\u6f0f\u5e94\u6025\u5904\u7406\u8bbe\u5907\u548c\u5408\u9002\u7684\u6536\u5bb9\u6750\u6599\u3002<\/p>\n<p>2.\u672c\u54c1\u9047\u660e\u706b\u71c3\u70e7\uff0c\u5e94\u8d2e\u4e8e\u9634\u51c9\u901a\u98ce\u5904\uff0c\u8fdc\u79bb\u706b\u6e90\uff0c\u70ed\u6e90\uff0c\u4e0e\u6c27\u5316\u5242\u5206\u5f00\u5b58\u653e\uff0c\u4e0e\u98df\u54c1\uff0c\u9972\u6599\uff0c\u79cd\u5b50\u5206\u5f00\u5b58\u653e\uff0c\u6ce8\u610f\u4fdd\u6301\u5305\u88c5\u5b8c\u6574\u3002\u6309\u6613\u71c3\u7269\u54c1\u89c4\u5b9a\u8d2e\u8fd0\u3002<\/p>\n<\/p>\n<h2 id=\"hc\">\u5408\u6210\u65b9\u6cd5<\/h2>\n<p><p>\u751f\u4ea7\u65b9\u6cd5\uff1a\u5176\u5236\u5907\u65b9\u6cd5\u6709\u4ee5\u4e0b\u51e0\u79cd\u3002<br \/>\u2460\u5bf9\u6c2f\u6cd5<br \/>\u5c06\u5bf9\u6c2f\u548c\u50ac\u5316\u5242ZrCl<sub>4<\/sub>\u653e\u5165\u53cd\u5e94\u5668\uff0c\u901a\u6c2f\u6c14\u8fdb\u884c\u6c2f\u5316\u53cd\u5e94\uff0c\u63a7\u5236\u901a\u6c2f\u6c14\u7684\u91cf\u81f3\u53cd\u5e94\u7ed3\u675f\uff0c\u505c\u6b62\u53cd\u5e94\uff0c\u5f97\u5230\u7684\u53cd\u5e94\u7269\u542b\u67092,4-\u4e8c\u6c2f85.1%\uff0c\u5982\u679c\u4ee5FeCl<sub>3<\/sub>\u4e3a\u50ac\u5316\u5242\u572810\uff5e15\u2103\u8fdb\u884c\u6c2f\u5316\u53cd\u5e94\u5230\u6eb6\u6db2\u76f8\u5bf9\u5bc6\u5ea6\u4e3a1.025\uff0c\u751f\u6210\u7269\u4e2d\u67092,4-\u4e8c\u6c2f\u548c3,4-\u4e8c\u6c2f\uff0c\u4e24\u7ec4\u5206\u8d28\u91cf\u6bd4\u4e3a100\u223630\u3002\u6c2f\u5316\u5b8c\u6bd5\u540e\u7528\u6c34\u6d17\u81f3\u4e2d\u6027\uff0c\u5e76\u752810\uff05NaOH\u6eb6\u6db2\u5728100\uff5e110\u2103\u4e0b\u5904\u7406\u4ee5\u9664\u53bb\u5176\u4ed6\u6742\u7269\uff0c\u7ecf\u5904\u7406\u540e\u7684\u6c2f\u5316\u7269\u5728\u9ad8\u6548\u7cbe\u998f\u5854\u8fdb\u884c\u7cbe\u998f\u5206\u79bb(2,4-\u4e8c\u6c2fb.p.200\u2103\uff0c3,4-\u4e8c\u6c2fb.p.207\u2103)\u30022,4-\u4e8c\u6c2f\u548c3,4-\u4e8c\u6c2f\u7684\u6536\u7387\u5206\u522b\u4e3a64.4%\u548c1 9.8%\u3002<\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"alignnone size-full wp-image-2640\" src=\"https:\/\/www.shorro.cn\/wp-content\/uploads\/2024\/05\/201009161546471734.gif\" width=\"177\" height=\"72\" alt=\"\" \/><br \/>\u2461\u90bb\u6c2f\u6cd5<br \/>\u90bb\u6c2f\u4ee5\u6c2f\u5316\u786b\u9170\u4e3a\u6c2f\u5316\u5242\u5728142\uff5e196\u2103\u4e0b\u8fdb\u884c\u6c2f\u5316\u53cd\u5e94\uff0c\u751f\u6210\u7269\u67092,4-\u4e8c\u6c2f\u548c2,3-\u4e8c\u6c2f\uff0c\u8fd8\u6709\u672a\u53cd\u5e94\u7684\u539f\u6599\uff0c\u5176\u7ec4\u6210\u5206\u522b\u4e3a55%\u30016%\u300139%\u3002\u7ecf\u8fc7\u84b8\u998f(2,4-\u4e8c\u6c2fb.p.200\u2103\uff0c2,3-\u4e8c\u6c2fb.p.207\uff5e208\u2103\uff0c\u90bb\u6c2fb.p.157\uff5e159\u2103)\u5206\u79bb\u5f97\u52302,4-\u4e8c\u6c2f\u3002<br \/>\u2462\u90bb\u785d\u57fa\u6cd5<br 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src=\"https:\/\/www.shorro.cn\/wp-content\/uploads\/2024\/05\/201009161547235288.gif\" width=\"232\" height=\"138\" alt=\"\" \/><br 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id=\"yt\">\u7528\u9014<\/h2>\n<p><p>1.\u519c\u836f\u4e2d\u95f4\u4f53\uff0c\u7528\u4e8e\u5236\u90202,4-\u4e8c\u6c2f\u82c4\u57fa\u6c2f\u30012,4-\u4e8c\u6c2f\u7532\u9170\u6c2f\u3002\u5728\u533b\u836f\u5de5\u4e1a\u7528\u4e8e\u5236\u9020\u6297\u759f\u836f\u963f\u7684\u5e73\u3002<\/p>\n<p>2.\u7528\u4f5c\u6eb6\u5242\uff0c\u7528\u4e8e\u5236\u836f\u53ca\u6709\u673a\u5408\u6210\u3002<sup>[22]<\/sup><\/p>\n<\/p>\n<p>    \t\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.morpholine.org\/catalyst-1028\/\">https:\/\/www.morpholine.org\/catalyst-1028\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.cyclohexylamine.net\/dabco-tl-low-odor-strong-foaming-tertiary-amine-catalyst\/\">https:\/\/www.cyclohexylamine.net\/dabco-tl-low-odor-strong-foaming-tertiary-amine-catalyst\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/dioctyl-dimaleate-di-n-octyl-tin\/\">https:\/\/www.bdmaee.net\/dioctyl-dimaleate-di-n-octyl-tin\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/dabco-33-lsi-dabco-33lsi\/\">https:\/\/www.bdmaee.net\/dabco-33-lsi-dabco-33lsi\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.newtopchem.com\/archives\/690\">https:\/\/www.newtopchem.com\/archives\/690<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/FASCAT4100-catalyst-monobutyl-tin-oxide-FASCAT-4100.pdf\">https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/FASCAT4100-catalyst-monobutyl-tin-oxide-FASCAT-4100.pdf<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/33-5.jpg\">https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/33-5.jpg<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.newtopchem.com\/archives\/40475\">https:\/\/www.newtopchem.com\/archives\/40475<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/fascat4201-catalyst-cas-818-08-6-dibutyl-tin-oxide\/\">https:\/\/www.bdmaee.net\/fascat4201-catalyst-cas-818-08-6-dibutyl-tin-oxide\/<\/a><\/br>\u6269\u5c55\u9605\u8bfb<a href=\"https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/37-2.jpg\">https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/37-2.jpg<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7ed3\u6784\u5f0f \u7269\u7ade\u7f16\u53f7 029P \u5206\u5b50\u5f0f C7H6Cl2 \u5206\u5b50\u91cf 161 \u6807\u7b7e 2,4-\u4e8c\u6c2f-1-\u7532\u57fa, 2,4-\u4e8c\u6c2f(\u4e8c\u6c2f), 2,4-\u4e8c\u6c2f-1-, 2,4-Dichloro-1-methylbenzene, 2,4-Dichloromethylbenzene, \u82b3\u9999\u65cf\u5364\u7d20\u884d\u751f\u7269 \u7f16\u53f7\u7cfb\u7edf \u7269\u6027\u6570\u636e \u6bd2\u7406\u5b66\u6570\u636e \u751f\u6001\u5b66\u6570\u636e 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